Title: NMR relaxation time measurements of solvent effects in an organocatalysed asymmetric aldol reaction over silica SBA-15 supported proline

Authors (6): G. Di Carmine, L. Forster, S. Wang, C. M. A. .Parlett, A. Carlone, C. D'Agostino

Themes: Core (2022)

DOI: 10.1039/d1re00471a

Citations: 14

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue: 2

License: [{"start"=>{"date-parts"=>[[2022, 5, 6]], "date-time"=>"2022-05-06T00:00:00Z", "timestamp"=>1651795200000}, "content-version"=>"vor", "delay-in-days"=>125, "URL"=>"http://creativecommons.org/licenses/by/3.0/"}]

Publication date(s): 2022/02/01 (print) 2022 (online)

Pages: 269-274

Volume: 7 Issue: 2

Journal: Reaction Chemistry & Engineering

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2022/RE/D1RE00471A", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d1re00471a

The behaviour of solvents in solid-supported proline organocatalysts is explored using NMR relaxation measurements coupled with reaction screening. Solvents with a lower affinity for the solid surface lead to a higher reactivity.

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