Publisher: Royal Society of Chemistry (RSC)

Issue: 27

License: [{"start"=>{"date-parts"=>[[2020, 6, 25]], "date-time"=>"2020-06-25T00:00:00Z", "timestamp"=>1593043200000}, "content-version"=>"vor", "delay-in-days"=>176, "URL"=>"http://creativecommons.org/licenses/by/3.0/"}]

Publication date(s): 2020/07/17 (print) 2020 (online)

Pages: 9495-9504

Volume: 49 Issue: 27

Journal: Dalton Transactions

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01960G", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d0dt01960g

Germylium-ylidene cations, [R(L)Ge]⁺, featuring amido substituents at R and NHC or phosphine donors at L have been synthesized and structurally characterized. The Lewis acidic germanium cation and proximal amide function allow for facile cleavage of N–H bonds in 1,2 fashion.