Title: Reversible borohydride formation from aluminium hydrides and {H(9-BBN)}2: structural, thermodynamic and reactivity studies

Authors (6): A. Caise, E. L. Kolychev, J. Hicks, M. ÁN. Fuentes, J. M. Goicoechea, S. Aldridge

Themes: Transformations (2019)

DOI: 10.1039/c9dt00535h

Citations: 6

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue: 29

License: [{"start"=>{"date-parts"=>[[2020, 2, 25]], "date-time"=>"2020-02-25T00:00:00Z", "timestamp"=>1582588800000}, "content-version"=>"am", "delay-in-days"=>420, "URL"=>"http://rsc.li/journals-terms-of-use"}]

Publication date(s): 2019/07/23 (print) 2019 (online)

Pages: 10845-10852

Volume: 48 Issue: 29

Journal: Dalton Transactions

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00535H", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/c9dt00535h

Aluminium borohydrides of the type (Nacnac)Al(R){H2(9-BBN)} are characterized by borane dissociation in solution under ambient conditions. This behaviour is critical to the ability of such complexes to reduce CO2.

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