Title: Heteroleptic, two-coordinate M(NHC){N(SiMe3)2}] (M = Co, Fe) complexes: synthesis, reactivity and magnetism rationalized by an unexpected metal oxidation state

Authors (11): A. A. Danopoulos, P. Braunstein, K. Y. Monakhov, J. van Leusen, P. Kögerler, M. Clémancey, J. -M. Latour, A. Benayad, M. Tromp, E. Rezabal, G. Frison

Themes: BAG (2017)

DOI: 10.1039/c6dt03565e

Citations: 26

Pub type: article-journal

Publisher: Royal Society of Chemistry (RSC)

Issue: 4

License:

Publication date(s): 2017 (online)

Pages: 1163-1171

Volume: 46 Issue: 4

Journal: Dalton Transactions

Link: http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT03565E

URL: http://dx.doi.org/10.1039/c6dt03565e

Magnetism, XPS and XANES data of the title complexes imply MII centres coupled to one ligand-delocalized electron.

Name Description Publised
c6dt03565e1.pdf Supl. data for Heteroleptic, two-coordinate M(NHC){N(SiMe3)2}] (M = Co, ... 2017
CCDC 1469263: Experimental Crystal Structure Determination Related Article: Andreas A. Danopoulos, Pierre Braunstein, Kirill Yu. Mo... 2017
CCDC 1469264: Experimental Crystal Structure Determination Related Article: Andreas A. Danopoulos, Pierre Braunstein, Kirill Yu. Mo... 2017
CCDC 1469265: Experimental Crystal Structure Determination Related Article: Andreas A. Danopoulos, Pierre Braunstein, Kirill Yu. Mo... 2017
CCDC 1469268: Experimental Crystal Structure Determination Related Article: Andreas A. Danopoulos, Pierre Braunstein, Kirill Yu. Mo... 2017
Supplementary Information File for Article Related Article: Heteroleptic, two-coordinate [M(NHC){N(SiMe3)2}] (M = C... 2016
Crystal Structure Data Related Article: Heteroleptic, two-coordinate [M(NHC){N(SiMe3)2}] (M = C... 2016


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