Title: ‘Switch’ catalysis: from monomer mixtures to sequence-controlled block copolymers

Authors (4): T. Stößer, T. T. . D. .Chen, Y. Zhu, C. K. Williams

Themes: Transformations (2018)

DOI: 10.1098/rsta.2017.0066

Citations: 62

Pub type: article-journal

Publisher: The Royal Society

Issue: 2110

License: http://royalsocietypublishing.org/licence

Publication date(s): 2018/01/13 (print) 2017/11/27 (online)

Pages: 20170066

Volume: 376 Issue: 2110

Journal: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences

Link: https://royalsocietypublishing.org/doi/pdf/10.1098/rsta.2017.0066

URL: http://dx.doi.org/10.1098/rsta.2017.0066

A ‘Switch’ catalysis method is reviewed whereby a single catalyst is switched between ring-opening polymerization and ring-opening copolymerization cycles. It allows the efficient synthesis of block copolymers from mixtures of lactones, epoxides, ...

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