Title: Ring opening polymerisation of lactide with uranium(iv) and cerium(iv) phosphinoaryloxide complexes

Authors (5): F. Sinclair, J. A. Hlina, J. A. L. .Wells, M. P. Shaver, P. L. Arnold

Themes: Transformations (2017)

DOI: 10.1039/c7dt02167d

Citations: 12

Pub type: article-journal

Publisher: Royal Society of Chemistry (RSC)

Issue: 33

License:

Publication date(s): 2017 (online)

Pages: 10786-10790

Volume: 46 Issue: 33

Journal: Dalton Transactions

Link: http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02167D

URL: http://dx.doi.org/10.1039/C7DT02167D

The C3-symmetric uranium(iv) and cerium(iv) complexes Me3SiOM(OArP)3, M = U (1), Ce (2), OArP = OC6H2-6-tBu-4-Me-2-PPh2, have been prepared and the difference between these 4f and 5f congeners as initiators for the ring opening polymerisation (ROP) of l-lactide is compared.

Name Description Publised
c7dt02167d1.pdf Supl. data for Ring opening polymerisation of lactide with uranium(iv) a... 2017
CCDC 1543395: Experimental Crystal Structure Determination Related Article: Fern Sinclair, Johann A. Hlina, Jordann A. L. Wells, Mi... 2017
CCDC 1543396: Experimental Crystal Structure Determination Related Article: Fern Sinclair, Johann A. Hlina, Jordann A. L. Wells, Mi... 2017


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