Title: Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst

Authors (8): I. B. Minova, M. Bühl, S. K. Matam, C. R. A. .Catlow, M. D. Frogley, G. Cinque, P. A. Wright, R. F. Howe

Themes: New Catalysts (2022)

DOI: 10.1039/d1cy02361f

Citations: 7

Pub type: journal-article

Publisher: Royal Society of Chemistry (RSC)

Issue:

License: [{"start"=>{"date-parts"=>[[2023, 2, 21]], "date-time"=>"2023-02-21T00:00:00Z", "timestamp"=>1676937600000}, "content-version"=>"am", "delay-in-days"=>416, "URL"=>"http://rsc.li/journals-terms-of-use"}]

Publication date(s): 2022 (online)

Pages:

Volume: Issue:

Journal: Catalysis Science & Technology

Link: [{"URL"=>"http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02361F", "content-type"=>"unspecified", "content-version"=>"vor", "intended-application"=>"similarity-checking"}]

URL: http://dx.doi.org/10.1039/d1cy02361f

In situ synchrotron infrared microspectroscopy on single crystals of SAPO-34 reveals that a carbene insertion mechanism is responsible for the first carbon–carbon bond formation from surface methoxy groups.

Name Description Publised
Carbene-like Reactivity of Methoxy Groups in a Single Crystal SAPO 34 MTO Catalyst (dataset) Data availabilityThe research data supporting this publication can be ac... 2022
supplementary (supplementary) for article Data availabilityThe research data supporting this publication can be ac... 2022


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