Catalyst design in oxidation chemistry  from KMnO4 to artificial metalloenzymes
Catalyst design in oxidation chemistry from KMnO4 to artificial metalloenzymes
Authors (5): M. V. Doble, A. C. C. Ward, P. J. Deuss, A. G. Jarvis, P. C. J. Kamer
Themes: Environment
DOI: 10.1016/j.bmc.2014.07.002
Citations: 28
Pub type: article-journal
Pub year: 2014

Publisher: Elsevier BV

Issue: 20

License: https://www.elsevier.com/tdm/userlicense/1.0/

Publication date(s): 2014/10 (print)

Pages: 5657-5677

Volume: 22 Issue: 20

Journal: Bioorganic & Medicinal Chemistry

Link: https://api.elsevier.com/content/article/PII:S0968089614005057?httpAccept=text/plain

URL: http://dx.doi.org/10.1016/j.bmc.2014.07.002

Oxidation reactions are an important part of the synthetic organic chemist’s toolkit and continued advancements have, in many cases, resulted in high yields and selectivities. This review aims to give an overview of the current state-of-the-art in oxygenation reactions using both chemical and enzymatic processes, the design principles applied to date and a possible future in the direction of hybrid catalysts combining the best of chemical and natural design.

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